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Nanoarchitectured Conjugated Microporous Polymers: State of the Art Synthetic Strategies and Opportunities for Adsorption Science

Nana Wan, Qingyun Chang, Fangyuan Hou, Shuaihua Zhang, Xiaohuan Zang, Xiaoxian Zhao, Chun Wang, Zhi Wang, Yusuke Yamauchi

2022Chemistry of Materials52 citationsDOI

Abstract

Conjugated microporous polymers (CMPs) have attracted extensive attention due to their permanent porosity, large specific surface area, unique thermal and chemical stability, and highly delocalized π–π conjugated skeleton. These outstanding characteristics give them a great potential for the applications in adsorption science and many other fields. This review summarizes the recent significant developments and breakthroughs in the synthesis of CMPs and their applications in the adsorption of a variety of compounds including gases, organic pollutants, heavy metal ions, etc. This review also highlights the efforts that the researchers have taken in the improvement of the adsorption performance of the CMPs. Meanwhile, the challenges that CMPs face in the field of adsorption are also discussed. Finally, the possible application directions of CMPs in the field of adsorption are also anticipated.

Topics & Concepts

Conjugated microporous polymerAdsorptionNanotechnologyMaterials scienceMicroporous materialConjugated systemDelocalized electronPolymerChemical engineeringOrganic chemistryChemistryEngineeringComposite materialCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas Transport