Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand
Jing Su, Thibault Cheisson, Alex McSkimming, Conrad A. P. Goodwin, Ida M. DiMucci, Thomas E. Albrecht‐Schmitt, Brian L. Scott, Enrique R. Batista, Andrew J. Gaunt, Stosh A. Kozimor, Ping Yang, Eric J. Schelter
Abstract
The coordination modes and electronic properties of a strongly coordinating hydroxylaminato ligand with Np, Pu and Am were investigated.Complexes were characterized by a range of experimental and computational techniques.
Topics & Concepts
ChemistryNeptuniumRedoxLigand (biochemistry)Oxidation stateCeriumActinideLanthanideElectrochemistryAmericiumCyclic voltammetryInorganic chemistryHomolepticNuclear chemistryPhysical chemistryIonMetalOrganic chemistryBiochemistryReceptorElectrodeRadioactive element chemistry and processingNuclear Materials and PropertiesChemical Synthesis and Characterization