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Critical screening parameters and critical behaviors of one-electron systems with screened Coulomb potentials

Li Guang Jiao, Hui Hui Xie, Aihua Liu, H. E. Montgomery, Y. K. Ho

2021Journal of Physics B Atomic Molecular and Optical Physics27 citationsDOIOpen Access PDF

Abstract

Abstract The critical screening parameters for one-electron systems screened by Hulthén, Debye–Hückel, and exponential cosine screened Coulomb potentials are calculated with an accuracy close to the precision of numerical arithmetic. The results for a H atom with an infinitely heavy nucleus are reported from the ground to high-lying excited states, and those for arbitrary two-body charged systems are derived from the Zm -scaling law. A thorough comparison of the critical screening parameters for the ground and the first p -wave excited states with previous predictions is made to demonstrate the accuracy of our calculations. The critical behaviors of system-bound and pseudo-continuum eigenenergies for s - and non- s -wave states are shown to follow the quadratic and linear laws, respectively. The variation of the corresponding wave functions is analyzed in detail. For systems with non-zero orbital angular momenta, the bound states convert into shape-type resonances when the screening parameter exceeds the critical value. The resonance energy shares the same linear law as the pseudo-continuum state, while the resonance width varies by an l -dependent power law. It is further shown that the different asymptotic behaviors of the resonance energy and width are consistent with the complex analog of the Hellmann–Feynman theorem.

Topics & Concepts

PhysicsExcited stateCoulombGround stateElectronWave functionExponential functionQuantum mechanicsResonance (particle physics)Atomic physicsBound stateQuantum electrodynamicsMathematical analysisMathematicsAdvanced Chemical Physics StudiesAtomic and Molecular PhysicsCold Atom Physics and Bose-Einstein Condensates
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