pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt(<scp>ii</scp>) molecular nanomagnet
Renato Rabelo, Luminita Marilena Toma, Nicolás Moliner, Miguel Julve, Francesc Lloret, Mario Inclán, Enrique García‐España, Jorge Pasán, Rafael Ruiz‐García, Joan Cano
Abstract
ion is partially lost and completely restored by pH decreasing and increasing. The fine-tuning of the optical, redox, and magnetic properties in this novel class of pH-responsive, spin crossover molecular nanomagnets offers fascinating possibilities for advanced multifunctional and multiresponsive magnetic devices for molecular spintronics and quantum computing such as pH-effect spin quantum transformers.
Topics & Concepts
ProtonationDeprotonationChemistrySpin crossoverTerpyridineRedoxCrystallographySpin statesLuminescenceSupramolecular chemistryMolecular switchPhotochemistryIonMoleculeMaterials scienceInorganic chemistryMetalCrystal structureOrganic chemistryOptoelectronicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry