Application of the stabilization effect of a silyl group in radical-polar crossover reactions enabled by photoredox-neutral catalysis
Naiyuan Yang, Yewen Fang, Fenfen Xu, Rong Zhou, Xiaoping Jin, Li Zhang, Jianxun Shi, Jianghua Fang, Hao Wu, Zongyong Zhang
Abstract
Taking advantage of the stabilization effect of a silyl group, with a bulky but positive nature, a range of less investigated organosilanes could be generally accessed via photoredox-catalysed radical-polar crossover reactions.
Topics & Concepts
SilylationChemistryPolarCrossoverGroup (periodic table)CatalysisPhotoredox catalysisPhotochemistryMedicinal chemistryOrganic chemistryPhotocatalysisPhysicsAstronomyArtificial intelligenceComputer scienceRadical Photochemical ReactionsPolyoxometalates: Synthesis and ApplicationsSulfur-Based Synthesis Techniques