Visible light-induced synthesis of 1,3-disubstituted bicyclo[1.1.1]pentane ketones<i>via</i>cooperative photoredox and N-heterocyclic carbene catalysis
Yan Gao, Zicong Zheng, Yu Zhu, Wenhao Xu, Yu Zhou, Chuanming Yu, Xinpeng Jiang
Abstract
Visible light-induced highly efficient synthesis of 1,3-disubstituted bicyclo[1.1.1]pentane with mild conditions, high atom economy, and superior functional group tolerance.
Topics & Concepts
PentaneBicyclic moleculeCarbeneAtom economyCatalysisChemistryVisible spectrumFunctional groupPhotochemistryCombinatorial chemistryMedicinal chemistryOrganic chemistryMaterials scienceOptoelectronicsPolymerCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry