Linker engineering of benzothiadiazole and its derivative-based covalent organic frameworks for efficient photocatalytic oxidative amine coupling and hydrogen peroxide generation
Chao-Qin Han, Jiaxin Guo, Lei Wang, Shuai Sun, Jie Lv, Xiaokang Sun, Hanlin Hu, Xiaoxi Huang, Xiao‐Yuan Liu
Abstract
Benzothiadiazole and its derivative-based COFs were prepared, in which benzothiadiazole-based COF exhibits superior photocatalytic aerobic oxidation of amine coupling, while the naphthothiadiazole-based COF shows the highest H 2 O 2 production rate.
Topics & Concepts
PhotocatalysisMaterials scienceHydrogen peroxideAmine gas treatingDerivative (finance)Covalent bondOxidative coupling of methaneLinkerCoupling (piping)PhotochemistryCovalent organic frameworkPolymer chemistryOrganic chemistryCatalysisChemistryComposite materialFinancial economicsComputer scienceOperating systemEconomicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications