Enhanced proton conductivity in a layered coordination polymer
Ricardo F. Mendes, Paula Barbosa, Eddy M. Domingues, Patrícia Silva, Filipe M. Figueiredo, Filipe A. Almeida Paz
Abstract
at 94 °C and 98% RH, still ranked as one of the highest reported values. Moreover, it is shown that the key factor for high proton conduction is the unusual dynamic structural transformation with water insertion and release of chloride ions.
Topics & Concepts
ConductivityProtonChlorideRelative humidityIonThermal conductionChemistryPolymerElectrical resistivity and conductivityHumidityAnalytical Chemistry (journal)Inorganic chemistryMaterials sciencePhysical chemistryThermodynamicsComposite materialOrganic chemistryPhysicsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsFuel Cells and Related MaterialsCovalent Organic Framework Applications