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Structural and Optical Properties of Solvated PbI<sub>2</sub> in γ-Butyrolactone: Insight into the Solution Chemistry of Lead Halide Perovskite Precursors

Eros Radicchi, Ali Kachmar, Edoardo Mosconi, Beatrice Bizzarri, Francesca Nunzi, Filippo De Angelis

2020The Journal of Physical Chemistry Letters25 citationsDOIOpen Access PDF

Abstract

-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) is also reported. The methodology developed in this work can be reasonably extended to the investigation of similar systems.

Topics & Concepts

Perovskite (structure)HalideChemistryDensity functional theoryDimethylformamideSolventDimethyl sulfoxideAbsorption (acoustics)Ab initioComputational chemistryAbsorption spectroscopySolvent effectsPhysical chemistryInorganic chemistryChemical physicsCrystallographyMaterials scienceOrganic chemistryPhysicsComposite materialQuantum mechanicsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyChalcogenide Semiconductor Thin Films
Structural and Optical Properties of Solvated PbI<sub>2</sub> in γ-Butyrolactone: Insight into the Solution Chemistry of Lead Halide Perovskite Precursors | Litcius