Magnetization Dynamics and Coherent Spin Manipulation of a Propeller Gd(III) Complex with the Smallest Helicene Ligand
Gabriela Handzlik, Michał Magott, Mirosław Arczyński, Alena M. Sheveleva, Floriana Tuna, Marcin Sarewicz, Artur Osyczka, Michał Rams, Veacheslav Vieru, Liviu F. Chibotaru, Dawid Pinkowicz
Abstract
cation is controlled mainly by a Raman process. Pulsed EPR experiments demonstrate long phase memory times (up to 2.7 μs at 5 K), enabling the detection of Rabi oscillations at 20 K, which confirms coherent control of its spin state.
Topics & Concepts
MagnetizationChemistryElectron paramagnetic resonanceRelaxation (psychology)Magnetization dynamicsHomolepticCondensed matter physicsNuclear magnetic resonancePhysicsMagnetic fieldQuantum mechanicsOrganic chemistrySocial psychologyPsychologyMetalMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications