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Long‐term atmospheric corrosion rates of Zn55Al‐coated steel

Dominique Thierry, Dan Persson, N. LeBozec

2024Materials and Corrosion8 citationsDOIOpen Access PDF

Abstract

Abstract Hot‐dip Zn55Al‐coated steel samples have been exposed for up to 6 years at 11 different weathering sites, including marine, marine‐industrial, acid‐rain and dry atmospheres. From the mass loss measurements, Zn55Al metallic coating showed globally long‐term good corrosion resistance in all weathering conditions compared with hot‐dip Zn‐0.2Al‐coated steel (Z). Yet, weaker performance was observed on Zn55Al in high SO 2 polluted atmosphere, particularly when combined with seawater aerosols. This is explained by a more acidic surface condition linked to high SO 2 . Although the extent of corrosion in this phase was different at the different sites, the final corrosion products formed after 6 years were rather similar at all sites. This consists of hydrous aluminium sulphate or hydrous aluminium hydroxy sulphate and, probably also a smaller amount of sulphate‐containing zinc corrosion products or Al/Zn products.

Topics & Concepts

CorrosionMetallurgySeawaterAluminiumWeatheringMetalCoatingAtmosphere (unit)ZincMaterials scienceAcid rainGalvanizationWeathering steelChemistryGeologyComposite materialLayer (electronics)GeochemistryMeteorologyOceanographyOrganic chemistryPhysicsCorrosion Behavior and InhibitionConcrete Corrosion and DurabilityHigh-Temperature Coating Behaviors