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Low temperature methanation of CO<sub>2</sub> over an amorphous cobalt-based catalyst

Jinghui Tu, Haihong Wu, Qingli Qian, Shitao Han, Mengen Chu, Shuaiqiang Jia, Ruting Feng, Jianxin Zhai, Mingyuan He, Buxing Han

2021Chemical Science58 citationsDOIOpen Access PDF

Abstract

methanation. The outstanding performance of the catalyst could be ascribed to two aspects. The amorphous nature of the catalyst offered abundant surface defects and intrinsic active sites. On the other hand, the Zr promoter could enlarge the surface area of the catalyst, enrich the Co atoms on the catalyst surface, and tune the valence state of the atoms at the catalyst surface. The reaction mechanism was proposed based on the control experiments.

Topics & Concepts

MethanationCobaltCatalysisAmorphous solidMaterials scienceChemical engineeringChemistryMetallurgyOrganic chemistryEngineeringCatalysts for Methane ReformingCarbon dioxide utilization in catalysisCatalytic Processes in Materials Science
Low temperature methanation of CO<sub>2</sub> over an amorphous cobalt-based catalyst | Litcius