Synthetic access to organyl-substituted 1,2,3-benzodiazaborines with turn-on fluorescence activity
Leonie Wüst, Johannes Chorbacher, Tim Wellnitz, Samuel Nees, Holger Helten, Holger Braunschweig
Abstract
). Overall, the synthetic approach presented herein expands the library of accessible DABs to alkyl and aryl derivatives and opens new possibilities to functionalize these BN-alkaloids for applications in fields like fluorescence sensing, material science, and medicinal chemistry.
Topics & Concepts
Turn (biochemistry)FluorescenceChemistryCombinatorial chemistryStereochemistryBiophysicsBiochemistryBiologyPhysicsQuantum mechanicsOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsRadical Photochemical Reactions