An iron-catalyzed multicomponent reaction of cycloketone oxime esters, alkenes, DABCO·(SO<sub>2</sub>)<sub>2</sub> and trimethylsilyl azide
Jun Zhang, Junwei Wu, Junwei Wu, Xiaotong Chang, Peiqi Wang, Jiemin Xia, Jie Wu, Jie Wu
Abstract
The synthesis of β-azidosulfones starting from alkenes, cycloketone oxime esters, trimethylsilyl azide and a sulfur dioxide surrogate of DABCO·(SO 2 ) 2 under iron catalysis is developed.
Topics & Concepts
ChemistryDABCOTrimethylsilyl azideOximeAzideCatalysisTrimethylsilylOrganic chemistrySulfurTrimethylsilyl cyanideSulfur dioxideSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsSynthesis and Catalytic Reactions