Synthesis of bicyclic vinyl triazenes by Ficini-type reactions
Carl Thomas Bormann, Farzaneh Fadaei‐Tirani, Rosario Scopelliti, Kay Severin
Abstract
AlCl, bicyclic [4.2.0] triazenes rearrange into [3.2.1] ring systems. The triazene function in the latter can be used for further functionalizations. Notably, we show that vinyl triazenes can serve as substrates for Pd-catalyzed cross-coupling reactions with arylboronic acids.
Topics & Concepts
TriazeneBicyclic moleculeChemistryCyclopentanoneCycloadditionCyclohexanoneReactivity (psychology)Organic chemistryLewis acids and basesCatalysisAlternative medicinePathologyMedicineCatalytic Alkyne ReactionsCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions