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Corrosion behavior and microstructural effects on passivation film mechanisms in forged Ti-5Al-5Mo-5V-1Cr-1Fe titanium alloy under laser surface remelting

Wenqi Lu, Yujing Liu, Xiang Wu, Xiaochun Liu, Jincheng Wang

2024Corrosion Science32 citationsDOIOpen Access PDF

Abstract

This study examines the corrosion behavior of Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511), comparing forged and LSRed (laser surface remelting) samples. LSR via 0.02 mm laser interval eliminates surface macro defects, enhances element homogenization, and converts primary and secondary α to β on forged Ti-55511 surface, yielding a thicker passivation film with higher stability than that of as-forged counterpart. This study investigates corrosion mechanisms by comparing the phase type, elemental homogeneity, grain size, morphology, and defects in relation to corrosion behavior. Galvanic corrosion predominates in the as-forged sample, with intensified pitting on the α phase and oxygen accumulation near α/β phase interface, while LSR-treated sample experiences β grain boundary corrosion. • LSR using an L-PBF homogenizes surface elemental distribution of forged TC18 and converts α p /α s phases into β. • The effect of LSR on the corrosion behavior of forged specimen was compared before and after treatment. • LSR effectively enhanced the corrosion resistance of forged specimen surface. • The influence of phase type, grain size, phase morphology and surface defect on corrosion was studied.

Topics & Concepts

PassivationCorrosionMaterials scienceMetallurgyTitanium alloyAlloyTitaniumLaserComposite materialOpticsPhysicsLayer (electronics)Additive Manufacturing Materials and ProcessesTitanium Alloys Microstructure and PropertiesHigh Entropy Alloys Studies