Highly luminescent olefin-linked covalent organic frameworks
Xinyu Wu, Lina Zong, Ning Huang
Abstract
-xylylenediphosphonate (TEXDP) as building blocks through a Horner-Wadsworth-Emmons reaction. By combination of the aromatic columnar ordering and high conjugation, the resulting TFB-TEXDP-COF exhibits a fluorescence quantum yield of up to 41%, which constitutes the new record value among COFs.
Topics & Concepts
Olefin fiberCovalent bondFluorescenceYield (engineering)Quantum yieldChemistryLuminescenceMaterials scienceNanotechnologyOrganic chemistryCatalysisOptoelectronicsOpticsPhysicsMetallurgyCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials