Diffusion mixing with a volatile tertiary amine as a very efficient technique for 1,3-dipolar cycloaddition reactions proceeding <i>via</i> dehydrohalogenation of stable precursors of reactive dipoles
Dmitry E. Shybanov, Maria E. Filkina, Maxim E. Kukushkin, Yuri K. Grishin, Vitaly A. Roznyatovsky, N. V. Zyk, Елена К. Белоглазкина
Abstract
Spontaneous diffusion of tertiary amine vapors into a dipolarophile precursor solution is the simplest technique for nitrilylide and nitrilimine generation in 1,3-cycloaddition reactions.
Topics & Concepts
ChemistryDehydrohalogenationMixing (physics)DiffusionAmine gas treatingCycloadditionDipoleTertiary amineChemical engineeringOrganic chemistryCombinatorial chemistryCatalysisThermodynamicsQuantum mechanicsPhysicsEngineeringChemical Synthesis and AnalysisFluorine in Organic ChemistryClick Chemistry and Applications