Graphite Nanoarrays-Confined Fe and Co Single-Atoms within Graphene Sponges as Bifunctional Oxygen Electrocatalyst for Ultralong Lasting Zinc-Air Battery
Chang Chen, Yifan Li, Dan Cheng, Hua He, Kebin Zhou
Abstract
The inferior stability of bifunctional oxygen electrocatalysts in the air cathode is one of the main obstacles that impedes the commercialization of zinc-air batteries (ZABs). This work describes a self-assembly technique combined with subsequent calcination to prepare a bifunctional oxygen electrocatalyst of graphite nanoarrays-confined Fe and Co single-atoms within graphene sponges (FeCo-NGS). Specifically, graphene sponges overspread with graphite nanoarrays as a structure regulation, which can prevent the metal single-atoms from aggregating and accelerate the mass/electron transfer, provides a guarantee for the long-term operation. Furthermore, M-N4 (M = Fe/Co) as the intrinsic activity regulation can effectively drive the heterogeneous oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalytic processes. Thanks to the rationally designed regulations, FeCo-NGS shows both extraordinary electrocatalytic activity for ORR and OER, even outperforming commercial Pt/C and IrO2. Remarkably, ZABs with FeCo-NGS air cathode demonstrate a record-breaking cycle lifetime of more than 1500 h (over 9000 cycles) at 10 mA cm–2 with a small charge–discharge gap.