Advances in two-dimensional materials for energy-efficient and molecular precise membranes for biohydrogen production
Ching Yoong Loh, Wenyuan Ye, Shengqiong Fang, Jiuyang Lin, Ailiang Gu, Xinyu Zhang, Andrew D. Burrows, Ming Xie
Abstract
Waste management has become an ever-increasing global issue due to population growth and rapid globalisation. For similar reasons, the greenhouse effect caused by fossil fuel combustion, is leading to chronic climate change issues. A novel approach, the waste-to-hydrogen process, is introduced to address the concern of waste generation and climate change with an additional merit of production of a renewable, higher energy density than fossil fuels and sustainable transportation fuel, hydrogen (H2) gas. In the downstream H2 purifying process, membrane separation is one of the appealing options for the waste-to-hydrogen process given its low energy consumption and low operational cost. However, commercial polymeric membranes have hindered membrane separation process due to their low separation performance. By introducing novel two-dimensional materials as substitutes, the limitation of purifying using conventional membranes can potentially be solved. Herein, this article provides a comprehensive review of two-dimensional materials as alternatives to membrane technology for the gas separation of H2 in waste-to-hydrogen downstream process. Moreover, this review article elaborates and provides some perspectives on the challenges and future potential of the waste-to-hydrogen process and the use of two-dimensional materials in membrane technology.