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Anisotropic Complex Refractive Indices of Atomically Thin Materials: Determination of the Optical Constants of Few-Layer Black Phosphorus

Aaron M. Ross, Giuseppe M. Paternò, Stefano Dal Conte, Francesco Scotognella, Eugenio Cinquanta

2020Materials13 citationsDOIOpen Access PDF

Abstract

In this work, studies of the optical constants of monolayer transition metal dichalcogenides and few-layer black phosphorus are briefly reviewed, with particular emphasis on the complex dielectric function and refractive index. Specifically, an estimate of the complex index of refraction of phosphorene and few-layer black phosphorus is given. The complex index of refraction of this material was extracted from differential reflectance data reported in the literature by employing a constrained Kramers-Kronig analysis combined with the transfer matrix method. The reflectance contrast of 1-3 layers of black phosphorus on a silicon dioxide/silicon substrate was then calculated using the extracted complex indices of refraction.

Topics & Concepts

PhosphoreneRefractive indexMaterials scienceBlack phosphorusMonolayerRefractionAnisotropySiliconSubstrate (aquarium)PhosphorusTransfer-matrix method (optics)DielectricOpticsTransition metalAnalytical Chemistry (journal)ReflectivityMatrix (chemical analysis)Layer (electronics)Molecular physicsThin layersThin filmConstant (computer programming)MineralogyOptoelectronicsPermittivityCondensed matter physicsTensor (intrinsic definition)Absorption (acoustics)2D Materials and ApplicationsPhase-change materials and chalcogenidesGraphene research and applications