Mixed-metal Zr/Ti MIL-173 porphyrinic metal–organic frameworks as efficient photocatalysts towards solar-driven overall water splitting
Ben Gikonyo, Eva Montero‐Lanzuela, Herme G. Baldoví, Siddhartha De, Catherine Journet, Thomas Devic, Nathalie Guillou, Davide Tiana, Sergio Navalón, Alexandra Fateeva
Abstract
A hydrolytically stable metal–organic framework containing Ti( iv ) and porphyrinic linkers allows a photoinduced charge separation process for the photocatalytic overall water splitting reaction.
Topics & Concepts
PhotocatalysisMetal-organic frameworkMetalMaterials scienceWater splittingPhotochemistryChemical engineeringChemistryCatalysisOrganic chemistryMetallurgyAdsorptionEngineeringAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCopper-based nanomaterials and applications