Impact of hydrogen bonding interaction energy on the polymerization kinetics of polymerizable deep eutectic solvent monomers
Liang Lin, Ren’ai Li, Guangxue Chen, Xiaochun Wang, Junhao Cheng, Jiali Zhao, Kai Zhao, Minghui He
Abstract
Research reveals that hydrogen bond is the primary factor contributing to the high activity of PDES monomer, while the steric effect within the PDES system weakens the activity of the PDES monomer by competing with the hydrogen bonding effect.
Topics & Concepts
MonomerDeep eutectic solventEutectic systemPolymer chemistryPolymerizationKineticsHydrogen bondSolventPhotopolymerChemistryMaterials scienceChemical engineeringPolymerOrganic chemistryMoleculeEngineeringPhysicsAlloyQuantum mechanicsIonic liquids properties and applicationsPolymer Nanocomposites and PropertiesAdvanced Polymer Synthesis and Characterization