Emerging Applications of Aryl Trifluoromethyl Diazoalkanes and Diazirines in Synthetic Transformations
Thierry Ollevier, Virginie Carreras
Abstract
groups and ease of synthetic access, aryl trifluoromethyl diazoalkanes and diazirines have been highlighted for their versatility in applications toward a wide range of synthetic transformations. This Perspective highlights the synthetic applications of these reactants as precursors of stabilized metal carbenes, i.e., donor-acceptor-substituted ones.
Topics & Concepts
TrifluoromethylArylChemistryCombinatorial chemistryAcceptorTrifluoromethylationOrganic chemistryCondensed matter physicsAlkylPhysicsCyclopropane Reaction MechanismsSynthesis and Catalytic ReactionsFluorine in Organic Chemistry