Solid-state<i>versus</i>solution investigation of a luminescent chiral BINOL-derived bisphosphate single-molecule magnet
Carlo Andrea Mattei, Vincent Montigaud, Frédéric Gendron, Sandrine Denis‐Quanquin, Vincent Dorcet, Nicolas Giraud, François Riobé, Gilles Argouarch, Olivier Maury, Boris Le Guennic, Olivier Cador, Claudia Lalli, Fabrice Pointillart
Abstract
The enantiopure coordination polymer [Dy(hfac)<sub>3</sub>(<bold>(S/R)-L</bold>)]<sub>n</sub>(<bold>[(S/R)-1]n</bold>) involving a BINOL-derived bisphosphate ligand<bold>(S/R)-L</bold>is investigated both in solution and solid-state.
Topics & Concepts
Enantiopure drugSolid-stateCrystallographyMoleculeCoordination polymerLigand (biochemistry)ChemistryMaterials sciencePhysicsPhysical chemistryOrganic chemistryCrystal structureBiochemistryCatalysisEnantioselective synthesisReceptorMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications