Highly selective 1-pentene epoxidation over Ti-MWW with modified microenvironment of Ti active sites
Jinpeng Yin, Hao Xu, Bowen Wang, Wenwen Tian, Jianyong Yin, Jingang Jiang, Peng Wu
Abstract
The hexa-coordinated Ti active sites with the piperidine molecules as ligand significantly accelerate H<sub>2</sub>O<sub>2</sub>activation, which effectively improve the catalytic performance of Ti-MWW in the 1-pentene epoxidation reaction.
Topics & Concepts
CatalysisPenteneLigand (biochemistry)ChemistryActive siteMoleculePiperidineCombinatorial chemistryStereochemistryOrganic chemistryReceptorBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials SciencePolyoxometalates: Synthesis and Applications