Redox-neutral decarboxylative coupling of fluoroalkyl carboxylic acids <i>via</i> dual metal photoelectrocatalysis
Yaxing Wu, Xiuling Wang, Zhenyu Wang, Chao Chen
Abstract
A photoelectrocatalytic method for the decarboxylative cross-coupling of α-CF 3 carboxylic acids has been established. Key to our approach is the strategic integration of the LMCT-induced decarboxylative process with classical nickel catalysis.
Topics & Concepts
Dual (grammatical number)RedoxMetalDual roleChemistryCoupling (piping)DecarboxylationCombinatorial chemistryPhotochemistryOrganic chemistryMaterials scienceCatalysisPhilosophyMetallurgyLinguisticsFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods