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Transformation Network Culminating in a Heteroleptic Cd<sub>6</sub>L<sub>6</sub>L′<sub>2</sub>Twisted Trigonal Prism

Dawei Zhang, Tanya K. Ronson, Lin Xu, Jonathan R. Nitschke

2020Journal of the American Chemical Society55 citationsDOIOpen Access PDF

Abstract

twisted trigonal prism. The principles underpinning this network thus allow for the design of diverse structural transformations, converting one helicate into another, a helicate into a tetrahedron, a tetrahedron into a different tetrahedron, and a tetrahedron into the new trigonal prismatic structure type. The selective conversion from one host to another also enabled the uptake of a desired guest from a mixture of guests.

Topics & Concepts

TetrahedronChemistryTrigonal crystal systemPrismTransformation (genetics)CrystallographyDisplacement (psychology)Trigonal prismatic molecular geometryCrystal structurePhysicsOpticsOctahedronBiochemistryGenePsychologyPsychotherapistSupramolecular Self-Assembly in MaterialsSupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and Applications