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Electroconductive and photoelectric properties of Pt/(100) β-Ga2O3 Schottky barrier diode based on Czochralski grown crystal

А. V. Аlmaev, В. И. Николаев, Nikita N. Yakovlev, P. N. Butenko, A. V. Tsymbalov, Michael Boiko, V. V. Kopyev, V. M. Krymov, Bogdan O. Kushnarev, Sevastian Shapenkov, М. Д. Шарков, Anton Zarichny

2024Journal of Vacuum Science & Technology A Vacuum Surfaces and Films18 citationsDOI

Abstract

Pt/(100) β-Ga2O3 Schottky barrier diodes were fabricated using a plate cleaved from the crystal grown by Czochralski method. Their electroconductive and photoelectric characteristics were studied. The following values were obtained: the Schottky barrier height (1.69/1.62/1.74 eV), ideality coefficient (1.09/1.14), saturation current density (9.91 × 10–15 A/cm2), diode series resistance (7.98 kΩ), and net donor concentration [(1.8–2.4) × 1018 cm–3]. The diodes demonstrate a high rectification ratio of 1010 at an applied voltage of ± 1 V and a relatively low experimental value of the leakage current density ∼10–11 A/cm2. These structures are solar-blind and also capable of operating in self-powered mode. The diodes are highly sensitive to short-wave ultraviolet radiation with a wavelength λ ≤ 265 nm. The maximum values of responsivity (20.4 A/W), external quantum efficiency (1.2 × 104%), and detectivity (9.6 × 1015 Hz0.5 × cm × W–1) of diodes were registered under exposure to irradiation at λ = 210 nm and at applied voltage of −1 V. The responsivity and external quantum efficiency values in the self-powered operation mode were 12.3 A/W and 7.2 × 103%, respectively. The diodes showed low rise and decay times in self-powered operation mode for photodiode based on Ga2O3: 14 and 30 ms, respectively.

Topics & Concepts

ResponsivityDiodeSchottky diodeSaturation currentMaterials scienceOptoelectronicsEquivalent series resistanceQuantum efficiencySchottky barrierPhotoelectric effectPhotodiodeCrystal (programming language)OpticsVoltageElectrical engineeringPhotodetectorPhysicsComputer scienceEngineeringProgramming languageGa2O3 and related materialsZnO doping and propertiesAdvanced Photocatalysis Techniques