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In‐Sublattice Carrier Transition Enabled Polarimetric Photodetectors with Reconfigurable Polarity Transition

Dongyan Li, Zexin Li, Yan Sun, Jian Zhou, Xiang Xu, Haoyun Wang, Yunxin Chen, Xingyu Song, Pengbin Liu, Zhengtang Luo, Su‐Ting Han, Xing Zhou, Tianyou Zhai

2024Advanced Materials25 citationsDOIOpen Access PDF

Abstract

Abstract Miniaturized polarimetric photodetectors based on anisotropic two‐dimensional materials attract potential applications in ultra‐compact polarimeters. However, these photodetectors are hindered by the small polarization ratio values and complicated artificial structures. Here, a novel polarization photodetector based on in‐sublattice carrier transition in the CdSb 2 Se 3 Br 2 /WSe 2 heterostructure, with a giant and reconfigurable PR value, is demonstrated. The unique periodic sublattice structure of CdSb 2 Se 3 Br 2 features an in‐sublattice carrier transition preferred along Sb 2 Se 3 chains. Leveraging on the in‐sublattice carrier transition in the CdSb 2 Se 3 Br 2 /WSe 2 heterostructure, gate voltage has an anisotropic modulation effect on the band alignment of heterostructure along sublattice. Consequently, the heterostructure exhibits a polarization‐tunable photo‐induced threshold voltage shift, which provides reconfigurable PR values from positive (unipolar regime) to negative (bipolar regime), covering all possible numbers (1→+∞/−∞→−1). Using this anisotropic photovoltaic effect, gate‐tunable polarimetric imaging is successfully implemented. This work provides a new platform for developing next‐generation highly polarimetric optoelectronics.

Topics & Concepts

PhotodetectorMaterials scienceHeterojunctionOptoelectronicsAnisotropyPolarimetryPolarization (electrochemistry)Condensed matter physicsOpticsPhysicsScatteringChemistryPhysical chemistry2D Materials and ApplicationsAdvanced Semiconductor Detectors and MaterialsPerovskite Materials and Applications