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Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(<scp>ii</scp>) tris-pyrazoloximates

Svetlana A. Belova, Alexander S. Belov, Anastasia A. Danshina, Yan V. Zubavichus, Dmitriy Yu. Aleshin, Alexander A. Pavlov, Nikolay N. Efimov, Yan Z. Voloshin

2023Dalton Transactions11 citationsDOI

Abstract

and an increase in the QTM contribution to the magnetic relaxation. The effect of a cross-linking halogenide counteranion on the Orbach remagnetization barrier is greater than that of the solvatomorphism of their crystals.

Topics & Concepts

CobaltCounterionSynthonChelationCrystallographyTrisLigand (biochemistry)ChemistryParamagnetismSingle crystalInorganic chemistryIonStereochemistryOrganic chemistryReceptorPhysicsBiochemistryQuantum mechanicsMagnetism in coordination complexesMetal complexes synthesis and propertiesMetal-Organic Frameworks: Synthesis and Applications
Effects of solvatomorphism, the nature of a chelating ligand synthon and a counterion on the single crystal XRD structure and SMM properties of paramagnetic monocapped cobalt(<scp>ii</scp>) tris-pyrazoloximates | Litcius