Solvent effects on Li ion transference number and dynamic ion correlations in glyme- and sulfolane-based molten Li salt solvates
Keisuke Shigenobu, Kaoru Dokko, Masayoshi Watanabe, Kazuhide Ueno
Abstract
dominate the ionic conduction for [Li(G4)][TFSA], Li ion hopping/exchange conduction was reported to be prevalent in the SL-based electrolytes. The unique Li ion conduction mechanism is considered to contribute to the less correlated cation-cation and cation-anion motions in SL-based electrolytes.
Topics & Concepts
SulfolaneIonMolten saltSalt (chemistry)ChemistrySolventThermodynamicsComputational chemistryInorganic chemistryChemical physicsPhysical chemistryOrganic chemistryPhysicsAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsAdvanced Battery Technologies Research