Carbon Dioxide Chemical Absorption Using Diamines with Different Types of Active Centers
Diego Gómez-Dı́az, José M. Navaza, Antonio Rumbo
Abstract
The present research analyzes chemical solvents based on the use of diamines (Ethylenediamine-EDA, 1,2-Dimethylethylenediamine-DMEDA and Tetramethylethylenediamine-TMEDA) for carbon dioxide absorption, taking into account the type of amino centers in the molecules. The presence and type of radicals can affect amine solubility in water, reaction mechanism, reaction kinetics, etc. Diamines have been considered interesting candidates for carbon dioxide chemical absorption, observing a high influence of the molecule structure. The present work analyzes a series of solvents based on diamines with the same chain length between amino centers, but different types of radicals. This study shows an important variability in the behavior of these solvents. EDA-based solvents have shown high absorption rates and stability, but carbamate hydrolysis is relatively low, avoiding an increase in carbon dioxide loading.