A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes
Jan Lorkowski, Melinda R. Serrato, Milan Gembicki, Marc Mauduit, Guy Bertrand, Rodolphe Jazzar
Abstract
Abstract The synthesis and characterization of cyclic (alkyl)(amino)carbene, bicyclic (alkyl)(amino)carbene and cyclic (amino)(barrelene)carbene copper (I) complexes is reported. These complexes are obtained via a scalable, versatile, green, and cost/user‐friendly strategy.
Topics & Concepts
CarbeneChemistryAlkylCopperBicyclic moleculeCombinatorial chemistryOrganic chemistryPolymer chemistryStereochemistryCatalysisN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsSynthetic Organic Chemistry Methods