Synthesis and characterization of cost-effective and high-efficiency biochar for the adsorption of Pb2+ from wastewater
Hatef Bassareh, Masoud Karamzadeh, Salman Movahedirad
Abstract
Abstract This study aimed to investigate the adsorption mechanism of Pb 2+ in wastewater using activated carbon derived from inexpensive materials, specifically avocado, bitter orange, and walnut leaves, through a single-step chemical activation process. The activated carbon was prepared using sulfuric acid as an activator, with a particle size of 1 mm. The pyrolysis reactor (slow-pyrolysis) operated at 600 °C for 90 min with a nitrogen flow rate of 5 L/min. Batch experiments were conducted under various conditions to determine the optimal dosage (1.5 g/L), equilibrium contact time (180 min), and pH (6.5). The study focused on employing cost-effective and highly efficient adsorbents, namely biochar produced from tree leaves, for the adsorption process. The results indicated that the pseudo-second-order kinetic model accurately described the adsorption process, while the Freundlich isotherm model best fit the experimental data. These findings suggest that tree leaves can serve as cost-effective and efficient adsorbents for a wide range of applications. Furthermore, multiple adsorption factors were evaluated in batch mode, including contact duration, pH, adsorbent dosage, concentration of the Pb 2+ solution, and temperature. The maximum adsorption capacities for the activated carbon derived from avocado, bitter orange, and walnut leaves were found to be 60.46, 59.42, and 58.48 mg/g, respectively. Thus, this study highlights the effectiveness and economic feasibility of using pyrolysis-derived activated carbon from low-cost materials for the removal of Pb 2+ from wastewater.