Copper‐Catalyzed Asymmetric Hydroallylation of Vinylsilanes
Simin Wang, Qiao Zhang, Junbo Niu, Xiaobing Guo, Tao Xiong, Qian Zhang
Abstract
Abstract A copper‐catalyzed asymmetric hydroallylation of readily available vinylsilanes with allylic phosphates in the presence of hydrosilane was developed. These transformations can be performed under mild reaction conditions and provide the useful chiral organosilanes with good to excellent level of enantiocontrol.
Topics & Concepts
ChemistryAllylic rearrangementCopperCatalysisOrganic chemistryCombinatorial chemistryOrganoboron and organosilicon chemistryAsymmetric Synthesis and CatalysisCatalytic C–H Functionalization Methods