The Redox Journey of Iconic Ferrocene: Ferrocenium Dications and Ferrocenate Anions
Mrinalini G. Walawalkar, Priya Pandey, Ramaswamy Murugavel
Abstract
The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C5 ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduced forms of ferrocene are of interest to spectroscopists, magnetochemists, and theoreticians.
Topics & Concepts
FerroceneRedoxChemistryRing (chemistry)MetalloceneSolventCombinatorial chemistryPolymer chemistryPhotochemistryOrganic chemistryElectrochemistryElectrodePhysical chemistryPolymerizationPolymerFerrocene Chemistry and ApplicationsMolecular Junctions and NanostructuresOrganometallic Complex Synthesis and Catalysis