Transition-Metal-Stabilized Heavy Tetraphospholide Anions
John A. Kelly, Verena Streitferdt, Maria Dimitrova, Franz F. Westermair, Ruth M. Gschwind, Raphael J. F. Berger, Robert Wolf
Abstract
, a specific type of symmetry-induced weak paramagnetism was found that is distinct from conventional antiaromatic species.
Topics & Concepts
ChemistryAntiaromaticityCyclopentadienyl complexTransition metalCrystallographyMetalCobaltParamagnetismGroup 2 organometallic chemistryAtomic orbitalWhite PhosphorusPhosphorusStereochemistryInorganic chemistryAromaticityMoleculeOrganic chemistryQuantum mechanicsCatalysisElectronPhysicsOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistry