Oxanorbornenes: promising new single addition monomers for the metathesis polymerization
Subhajit Pal, Mahshid Alizadeh, Phally Kong, Andreas F. M. Kilbinger
Abstract
Bridgehead revisited: <italic>endo</italic>-7-oxa norborneneimide derivatives (green) initiate faster but propagate more slowly than the analogous <italic>exo</italic>-derivatives (red) in ring-opening metathesis allowing the synthesis of alternating and end functional polymers.
Topics & Concepts
MetathesisRing-opening metathesis polymerisationMonomerPolymerizationSalt metathesis reactionAcyclic diene metathesisPolymerChemistryOrganic chemistrySynthetic Organic Chemistry MethodsChemical Synthesis and AnalysisOrganometallic Complex Synthesis and Catalysis