Bridging two worlds: (DABCO-H)CuKI<sub>3</sub> a hybrid copper iodide phosphor with a perovskite structure
Lidia Armelao, Maria Rando, Silvia Carlotto, Irene Motta, Gregorio Bottaro, Marzio Rancan
Abstract
Abstract A novel copper iodide hybrid compound, (DABCO-H)CuKI 3 , featuring a perovskite structure is here reported. Characterization techniques, including single crystal X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and photoluminescence studies, elucidate the structural and luminescent properties. The compound exhibits blue phosphorescence, attributed to mixed metal-to-ligand and halide-to-ligand charge transfer transitions, as supported by density functional theory (DFT) calculations and XPS valence band analysis. Furthermore, (DABCO-H)CuKI 3 displays a remarkable adsorption capacity towards methylene blue dye. Kinetic modelling reveals that both film and intra-particle diffusion processes contribute to the adsorption rate.