Solvent-modulated binding selectivity of reaction substrates to onium-based σ-hole donors
Alexandra A. Sysoeva, Alexander S. Novikov, Mikhail V. Il’in, Dmitrii S. Bolotin
Abstract
Solvation effects might play the dominant role in the catalysis providing an increase or suppression of the activity of the organocatalysts.
Topics & Concepts
OniumSelectivityCatalysisSolvationChemistrySolventSolvent effectsCombinatorial chemistryComputational chemistryPhotochemistryOrganic chemistryIonAsymmetric Synthesis and CatalysisCrystallography and molecular interactionsChemical Synthesis and Analysis