Hydrogen-Induced Aggregation of Au@Pd Nanoparticles for Eye-Readable Plasmonic Hydrogen Sensors
Chao Li, Huili Zhu, Yu Guo, Shunsheng Ye, Tieqiang Wang, Yu Fu, Xuemin Zhang
Abstract
Plasmonic materials provide a promising platform for optical hydrogen detection, but their sensitivities remain limited. Herein, a new type of eye-readable H2 sensor based on Au@Pd core–shell nanoparticle arrays (NAs) is reported. After exposed to 2% H2, Au@Pd (16/2) NAs demonstrate a dramatic decrease in the optical extinction intensity, along with an obvious color change from turquoise to gray. Experimental results and theoretical calculations prove that the huge optical change resulted from the H2-induced aggregation of Au@Pd nanoparticles (NPs), which remarkably alters the plasmon coupling effect between NPs. Moreover, we optimize the sensing behavior from two aspects. The first is selecting appropriate substrates (either rigid glass substrate or flexible polyethylene terephthalate substrate) to offer moderate adhesion force to NAs, ensuring an efficient aggregation of Au@Pd NPs upon H2 exposure. The second is adjusting the Pd shell thickness to control the extent of NP aggregation and thus the detection range of the as-prepared sensors. This work highlights the advantage of designing eye-readable plasmonic H2 sensors from the aspect of tuning the interparticle plasmonic coupling in NP assemblies. Au@Pd NAs presented here have several advantages in terms of simple fabrication method, eye-readability in air background at room temperature, tunable detection range, and high cost-effectiveness.