Litcius/Paper detail

Carbodiimide-fueled catalytic reaction cycles to regulate supramolecular processes

Patrick Schwarz, Marta Tena‐Solsona, Kun Dai, Job Boekhoven

2021Chemical Communications65 citationsDOI

Abstract

, temporal and spatial control and self-healing ability. Thus, to synthesize life-like materials, we have to find a reaction cycle that converts chemical energy to regulate self-assembly. We and others recently found that this can be done by a reaction cycle that hydrates carbodiimides. This feature article aims to provide an overview of how the energy transduced from carbodiimide hydration can alter the function of molecules and regulate molecular assemblies. The goal is to offer the reader design considerations for carbodiimide-driven reaction cycles to create a desired morphology or function of the assembly and ultimately to push chemically fueled self-assembly further towards the bottom-up synthesis of life.

Topics & Concepts

CarbodiimideSupramolecular chemistrySupramolecular assemblyNanotechnologyMoleculeCatalysisChemistryMaterials scienceCombinatorial chemistryOrganic chemistrySupramolecular Self-Assembly in MaterialsSupramolecular Chemistry and ComplexesMicrotubule and mitosis dynamics