Electrochemical oxidative thiocyanation and amination of enaminones towards the synthesis of multi-substituted alkenes
Fangling Lu, Kan Zhang, Yanxiu Yao, Ying Yin, Jiafu Chen, Xinwei Zhang, Yin Wang, Lijun Lu, Ziwei Gao, Aiwen Lei
Abstract
A highly stereoselective synthesis of thiocyanated enaminones was achieved by an electrochemical process, which involved C–H bond thiocyanation and vinyl C–N bond transamination.
Topics & Concepts
AminationChemistryTransaminationElectrochemistryStereoselectivityOxidative phosphorylationDouble bondCombinatorial chemistryOrganic chemistryCatalysisElectrodeEnzymePhysical chemistryBiochemistrySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCatalytic C–H Functionalization Methods