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Copper with an atomic-scale spacing for efficient electrocatalytic co-reduction of carbon dioxide and nitrate to urea

Seokmin Shin, Siraj Sultan, Zong‐Xian Chen, Hojeong Lee, Hojeong Lee, Hansaem Choi, Tae‐Ung Wi, Chang-Hyun Park, Tae‐Won Kim, Chanhee Lee, Jihong Jeong, Hyeju Shin, Taehee Kim, HyungKuk Ju, Hyung Chul Yoon, Hyun‐Kon Song, Hyun‐Wook Lee, Hyun‐Wook Lee, Mu‐Jeng Cheng, Youngkook Kwon

2023Energy & Environmental Science142 citationsDOI

Abstract

This work presents that Cu with atomic-scale spacings ( d s ) efficiently catalyses the electrochemical co-reduction of CO 2 and NO 3 − to urea. Specifically, Cu with d s near 6 Å (6 Å-Cu) produces urea with a high yield rate and partial current density.

Topics & Concepts

UreaElectrochemistryCopperYield (engineering)Inorganic chemistryChemistryReduction (mathematics)Carbon dioxideNitrateCatalysisAtomic unitsCurrent densityMaterials scienceElectrodePhysical chemistryMetallurgyMathematicsOrganic chemistryPhysicsQuantum mechanicsGeometryAmmonia Synthesis and Nitrogen ReductionCO2 Reduction Techniques and CatalystsAdvanced Photocatalysis Techniques
Copper with an atomic-scale spacing for efficient electrocatalytic co-reduction of carbon dioxide and nitrate to urea | Litcius