Catalyst-Enabled <i>In Situ</i> Linkage Reduction in Imine Covalent Organic Frameworks
Ji‐Yun Hu, Federica Zanca, Gregory J. McManus, Isabella A. Riha, Huong Giang T. Nguyen, William M. Shirley, Collin G. Borcik, Benjamin J. Wylie, Mourad Benamara, Roger D. van Zee, Peyman Z. Moghadam, M. Hassan Beyzavi
Abstract
reduced to the amine COF by the reductive P-H moiety. The amine-linked COF outperforms its imine analogue in promoting Knoevenagel condensation because of the more basic sites and higher stability.
Topics & Concepts
ImineAmine gas treatingMoietyCovalent bondBifunctionalKnoevenagel condensationCovalent organic frameworkCatalysisAldehydeCombinatorial chemistryMaterials scienceOrganic chemistryChemistryCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques