A POM-based porous supramolecular framework for efficient sulfide–sulfoxide transformations with a low molar O/S ratio
Yanhong Chen, Haiyan An, Shenzhen Chang, Yanqin Li, Qingshan Zhu, Huiyun Luo, Yao-Hui Huang
Abstract
A porous supramolecular framework heterogeneously catalyzed the oxidative synthesis of sulfoxides and the detoxification of mustard gas simulants with a low molar O/S ratio.
Topics & Concepts
Molar ratioSulfideSupramolecular chemistrySulfoxidePorosityMolarDimethyl sulfoxideChemistryChemical engineeringMaterials scienceOrganic chemistryMoleculeGeologyCatalysisPaleontologyEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and ReactionsPolyoxometalates: Synthesis and Applications