A perylene monoimide probe based fluorescent micelle sensor for the selective and sensitive detection of picric acid
Weiqing Li, Huipeng Zhou, Muhammad Azhar Hayat Nawaz, Niu Niu, Na Yang, Jia Ren, Cong Yu
Abstract
A hydroxyl functionalized perylene monoimide probe (PMI-OH) was prepared and self-assembled with the nonionic surfactant Triton X-100 (TX100) to fabricate a fluorescent micelle sensor for the selective and sensitive detection of picric acid (PA), a common explosive and environmental pollutant. The synthesized PMI-OH probe exhibited excimer fluorescence emission, and the intensity of the excimer fluorescence emission was significantly enhanced after the PMI-OH probe formed micelles with TX100. The obtained PMI-OH@TX100 micelles presented excellent photoluminescence properties and had a maximum fluorescence emission at 630 nm. The red fluorescence of the PMI-OH@TX100 micelles was quenched upon introduction of the nitro explosive PA due to electron transfer from the donor (PMI-OH) to the acceptor (PA). The fluorescence quenching of the fluorescent micelle sensor was proportional to the concentration of PA in the range of 2 to 10 μM. The limit of detection was 500 nM using 3σ/k. Thus, the developed PMI-OH@TX100 micelle sensor has great potential to detect PA in ordinary samples.