Nanocage-based {In<sub>2</sub>Tm<sub>2</sub>}-organic framework for efficiently catalyzing the cycloaddition reaction of CO<sub>2</sub> with epoxides and Knoevenagel condensation
Hongxiao Lv, Hongtai Chen, Tuoping Hu, Xiutang Zhang
Abstract
The combination of [In 2 Tm 2 (μ 2 -OH) 2 (CO 2 ) 10 (H 2 O) 2 ] clusters and H 5 BDCP ligand generated a highly robust nanoporous MOF with high catalytic performance in the cycloaddition reaction of epoxides with CO 2 and Knoevenagel condensation.
Topics & Concepts
Knoevenagel condensationCycloadditionCatalysisNanoporousChemistryNanocagesLigand (biochemistry)CondensationOrganic chemistryPhysicsThermodynamicsReceptorBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisMachine Learning in Materials Science