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A new breakthrough in low-coordinate Dy(<scp>iii</scp>) single-molecule magnets

Zhenhua Zhu, Ying Xu, Chen Zhao, Yi‐Quan Zhang, Jinkui Tang

2022Inorganic Chemistry Frontiers38 citationsDOI

Abstract

A five-coordinate mononuclear Dy( iii ) complex was constructed using a super bulky Schiff-base ligand, which shows a strong block of magnetization with a U eff of ca. 1200 cm −1 and a T B of 20 K.

Topics & Concepts

MagnetizationLigand (biochemistry)MagnetMoleculeCrystallographyBlock (permutation group theory)Schiff baseMaterials scienceSingle-molecule magnetChemistryPhysicsMagnetic fieldGeometryMathematicsOrganic chemistryReceptorQuantum mechanicsBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research
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